Moléculas con la misma geometría pero distintas propiedades electrónicas
una breve revisión del fulereno mono-endoédrico (La, Gd, Sc, Eu)@C82
Keywords:
C82 Fullerene, (La, Gd, Sc, and Eu)@C82, molecular structure, electronic properties
Abstract
In the present work, a brief synthesis of the results of the endohedral C82 fullerene with a single atom inside will be carried out. Specifically, the M@C82 (M=La, Gd, Sc, and Eu) will be reviewed. The results in the scientific literature show that the endohedral atom’s position in the fullerene is the same for each compound. However, the properties obtained from these nanostructures are different, thus demonstrating the importance of knowledge of the electronic arrangement of the molecules.
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References
Akasaka, T., Wakahara, T., Nagase, S., Kobayashi, K., Waelchli, M., Yamamoto, K., ... y Kadish, K. M., La@C82 Anion. An Unusually Stable Metallofullerene. J. Of the American Chemical Society, 122(38), pp.9316-9317, 2000. doi: 10.1021/ja001586s
Chai, Y., Guo, T., Jin, C., Haufler, R. E., Chibante, L. F., Fure, J., ... y Smalley, R. E., Fullerenes with metals inside. The Journal of Physical Chemistry, 95(20), pp.7564- 7568, 1991. doi: 10.1021/ j100173a002
Huang, H., y Yang, S., Relative Yields of Endohedral Lanthanide Metallofullerenes by Arc Synthesis and their Correlation with the Elution Behavior. J. Phys. Chem., 102, pp.10196-10200, 1998. doi: 10.1021/jp982926n
Kroto, H. W., Heath, J. R., O’Brien, S. C., Curl, R. F., y Smalley, R. E., C60: Buckminsterfullerene. Nature, 318(6042), pp.162-163, 1985. doi: 10.1038/318162a0
Manolopoulos, D. E., y Fowler, P. W., Molecular Graphs, Point Groups, and Ful l e - renes. J. Phys. Chem., 96(10), pp.7603- 7614, 1992. doi: 10.1063/1.462413
Mizorogi, N., y Nagase, S., Do Eu@C82 and Gd@C82 have an anomalous endohedral structure?. Chemical Physics Letters, 431, pp.110-112, 2006. doi: 10.1016/j.cplett. 2006.09.046
Nishibori, E., Takata, M., Sakata, M., Inakuma, M., y Shinohara, H., Det e rmination of the Cage Structure of Sc@C82 by Synchrotron Powder Diffraction. Chemical Physics Letters, 298, pp.79-84, 1998. doi: 10.1016/S0009-2614(98)01133-6
Popov, A. A., Yang, Sh., y Dunsch, L., Endohedral Fullerenes. Chemical Reviews, 113, pp.5989-6113, 2013. doi: 10.1021/ cr300297r
Rodríguez-Zavala, J. G. Tenorio, F. J., Samaniego, C., Méndez-Barrientos, C. I., Peña- Lecona, F. G., Muñoz-Maciel, J., y Flores-Moreno, R., Theoretical Study on the Sequential Hydroxylation of C82 Fullerene Based on Fukui Function. Molecular Physics, 109(14), pp.1771-1783, 2011. doi: 10.1080/00268976.2011.591743
Suzuki, M., Lu, X., Sato, S., Nikawa, H., Mizorogi, N., Slanina, Z., ... y Akasaka, T., Where does the Metal Cation Stay in Gd@C2v(9)-C82? A Single-Crystal X-ray Diffraction Study. Inorganic Chemistry, 51, pp.5270-5273, 2012. doi: 10.1021/ ic300186y
Chai, Y., Guo, T., Jin, C., Haufler, R. E., Chibante, L. F., Fure, J., ... y Smalley, R. E., Fullerenes with metals inside. The Journal of Physical Chemistry, 95(20), pp.7564- 7568, 1991. doi: 10.1021/ j100173a002
Huang, H., y Yang, S., Relative Yields of Endohedral Lanthanide Metallofullerenes by Arc Synthesis and their Correlation with the Elution Behavior. J. Phys. Chem., 102, pp.10196-10200, 1998. doi: 10.1021/jp982926n
Kroto, H. W., Heath, J. R., O’Brien, S. C., Curl, R. F., y Smalley, R. E., C60: Buckminsterfullerene. Nature, 318(6042), pp.162-163, 1985. doi: 10.1038/318162a0
Manolopoulos, D. E., y Fowler, P. W., Molecular Graphs, Point Groups, and Ful l e - renes. J. Phys. Chem., 96(10), pp.7603- 7614, 1992. doi: 10.1063/1.462413
Mizorogi, N., y Nagase, S., Do Eu@C82 and Gd@C82 have an anomalous endohedral structure?. Chemical Physics Letters, 431, pp.110-112, 2006. doi: 10.1016/j.cplett. 2006.09.046
Nishibori, E., Takata, M., Sakata, M., Inakuma, M., y Shinohara, H., Det e rmination of the Cage Structure of Sc@C82 by Synchrotron Powder Diffraction. Chemical Physics Letters, 298, pp.79-84, 1998. doi: 10.1016/S0009-2614(98)01133-6
Popov, A. A., Yang, Sh., y Dunsch, L., Endohedral Fullerenes. Chemical Reviews, 113, pp.5989-6113, 2013. doi: 10.1021/ cr300297r
Rodríguez-Zavala, J. G. Tenorio, F. J., Samaniego, C., Méndez-Barrientos, C. I., Peña- Lecona, F. G., Muñoz-Maciel, J., y Flores-Moreno, R., Theoretical Study on the Sequential Hydroxylation of C82 Fullerene Based on Fukui Function. Molecular Physics, 109(14), pp.1771-1783, 2011. doi: 10.1080/00268976.2011.591743
Suzuki, M., Lu, X., Sato, S., Nikawa, H., Mizorogi, N., Slanina, Z., ... y Akasaka, T., Where does the Metal Cation Stay in Gd@C2v(9)-C82? A Single-Crystal X-ray Diffraction Study. Inorganic Chemistry, 51, pp.5270-5273, 2012. doi: 10.1021/ ic300186y
Published
2024-10-03
How to Cite
Rodríguez Zavala, J. G., Cisneros García, Z. N., & Romo Gutiérrez, A. (2024). Moléculas con la misma geometría pero distintas propiedades electrónicas: una breve revisión del fulereno mono-endoédrico (La, Gd, Sc, Eu)@C82. Contactos, Revista De Educación En Ciencias E Ingeniería, (134), 93 - 98. Retrieved from https://contactos.izt.uam.mx/index.php/contactos/article/view/417
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